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1° alkyl halide + stong nucleophile |
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1° alkyl halide + strong, hindered base (tBuO-) |
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1º alkyl halide + weak base or nucleophile |
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2º alkyle halide + strong nucleophile |
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2º alkyl halide + Strong, hindered base tBuO-
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2º alkyl halide + weak base or nucleophile |
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3º alkyl halide + weak base or nucleophile |
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3º alkyl halide + strong base |
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3º alkyl halide + strong nucleophile |
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PCC used with ___ to ____ |
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Definition
PCC is used with CH2Cl2 to oxidize to ketone but not carboxylic acid |
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Definition
takes off halogen in cyclopentanes |
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R-C2C−+ [image]
(all other C bonds are to H) |
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Poisened Catalyst + Alkyne + H2 |
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K2Cr2O7 uses ____ to ____ |
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Definition
K2Cr2O7 uses H2SO4 to oxidize |
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Definition
1,2 Addn
1, 4 addn product both produced |
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Definition
Use CH3CHOOOH
3 oxygens (per) |
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A down equitorial is equal is CIS to |
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Alc. dehydration
ether formation |
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R
R-C-O-MgBr
R
bolded from ketone |
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Producing Epoxides requires what solvent |
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In the more stable molecule, more or less heat is released when burned |
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[image]
notice trans conformation in final product |
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what produces triple bond anion |
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What cyclopentane reactant keeps cis groups cis and trans groups trans |
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Term
What makes a molecule more basic? |
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Definition
Less electroneg groups because they are more likely to give away electrons.
so CH3NH2 better base than CH3OH |
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