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it is the branch of chemistry concerned with energy changes |
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What is potiential energy? |
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Name the forms of energy? |
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Definition
mechanical, heat, sound, electric, light, or radioactive |
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it is the amount of heat energy required to raised one gram of water one degree celsius |
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What is calorie labeled with a captail C? |
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What is an oxidation-reduction reaction? |
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Definition
loss or gain of an electron in a reaction |
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what is the first law of thermodynamics? |
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energy cannot be neither created nor destroyed |
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What is the second law of thermodynamics? |
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Definition
entropy is constantly increasing in the universe |
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the disorder in the universe |
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the amount of energy avaliable to do work |
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the energy used to make and break bonds |
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What is endergonic energy? |
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Definition
the inward energy, requires an input of energy |
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What is exergonic energy? |
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Definition
outward energy, releases excess free energy |
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What is the difference of equilibrum favoring of exergonic and endergonic reactions? |
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Definition
exergonic has an equilibrum favoring the products, and endergonic has an equilibrium favoring the reactants |
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what is activation energy? |
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Definition
the extra energy needed to destabilize existing chemical bonds and intiate a chemical reaction |
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As the activation energy lowers what happens to the reaction rate? |
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What can lower the activation energy? |
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The rate of the reaction can be increased by what two things? |
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Definition
increasing the energy of reacting molecules and lowering the activation energy |
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the process of influencing chemical bonds in a way that lowers the activation energy needed to initiate a reaction. |
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ATP is the building block for what? |
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Definition
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a five carbon sugar (ribose), adenine, and a chain of 3 phosphates |
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What is the key to understanding how ATP stores energy? |
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Definition
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Phosphate groups are what kind of charge? |
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Definition
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What four things effect enzymes? |
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Definition
temperature, pH, inhibitors, and activators |
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Definition
when ATPS outermost energy phosphate bond is hydroylzed, cleaving off the phosphate group on the end |
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Cells use ATP to drive what type of reaction? |
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Definition
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Describe the cyclic fashion of ATP. |
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Definition
Cells use exergonic reactions to provide the energy needed to synthesize ATP from ADP +Pi. They then could use the hydrolysis of ATP to provide energy to drive the endergonic reactions needed. |
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How much ATP is generally stored? |
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Definition
a few second supply, but it constatantly making ADP |
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What does the 3-D shape of an enzyme enable? |
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Definition
It stabalizes a temporary association between substrates |
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Definition
the molecules that will undergo the reaction |
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Definition
the pockets in globular proteins with clefts |
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How does induced fit work? |
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Definition
it is the bondage between the substrate and the enzyme |
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What is the multienzyme complex? |
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Definition
It is an assembly consisting of several enzymes catalyzing different steps in a sequence of reactions |
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what is intramolecular catalysis? |
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Definition
ribosomes that have folded structures and catalyze reactions on themselves |
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what is intramolecular catalysis? |
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Definition
other ribozymes act on other molecules without being changed themselves |
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what is the optimum temperature? |
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Definition
the highest temperature an enzyme-catalyzed reaction can reach |
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What is the human enzyme optimum temperature? |
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Definition
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what is one way enzymes are held together? |
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Definition
between oppositely charged amino acids |
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What does the optimum pH for enzymes usually range from? |
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Definition
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Definition
a substance that binds to an enzyme and decreases its activity |
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What is the feedback inhibition? |
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Definition
the end product is used as an inhibitor |
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What is a competitive inhibitors? |
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Definition
they compete with the substrate for the same active site, occupying the active site and preventing substrates from binding |
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What are noncompetitive inhibitors? |
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Definition
they bind to the enzyme in a location other than the active site |
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What is allosteric enzymes? |
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Definition
enzymes that exist either as an active or inactive conformation |
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Where does most noncompetitive inhibitors bind to? |
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Definition
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What is an allosteric inhibitor? |
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Definition
a substance that binds to an allosteric site and reduces enzyme activity |
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Term
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Definition
additional chemical componenets that help with enzyme function |
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a cofactor that is a nonprotein organic molecule |
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total of all chemical reactions carried out by an organism |
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Definition
chemical reactions that expend energy to build up molecules |
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What is a biological pathway and what is an example of it? |
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Definition
a sequence of chemical reactions in which the product of one reaction becomes the substrate of the next reaction , and the krebs cycle |
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