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Hazardous Materials Terminology
HAZMAT Tech Definitions
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Professional
06/28/2011

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Term
Caustic
Definition
Capable of burning, corroding, dissolving, or eating away by chemical action. pH greater than 7 in its standard state.
Term
Auto-refrigeration
Definition
A phenomenon that occurs during the rapid release (boiling) of a liquified gas that causes it to temporarily remain in a liquid state through rapid cooling. RISK: False assumption of product elimination until the product resumes boiling and subsequent release.
Term
Biological agents
Definition
Producing disease through living microorganisms that can mutate and become toxins are more deadly.
Term
Biological toxins
Definition
Toxins can be small molecules, peptides, or proteins that are capable of causing dises on contact with or absorption by body tissues. RISK: Affects human health in a variety of ways ranging from allergic reactions to death.
Term
ACID
Definition
Any substance whose aqueous solutions are characterized by a sourt taste, the ability to turn blue litmus red, and the ability to react with bases and certain metals to form salts. pH less than 7 in its standard state.
Term
Blood agents
Definition
A chemical compound, including the cyanide group, that affects bodily functions by preventing the normal utilization of oxygen by body tissues. The term "blood agent" is a misnomer, however, because these agents to not actually affect the blood in anyway instead affects hemoglobin.
Term
Boiling Point
Definition
Temperature at which the transition from a liquid to a gast state occurs. At this temperature, the vapor pressure of a liquid equals the surrounding atmospheric pressure so that the liquid rapidly becomes a vapor.
Term
Catalyst
Definition
A substance that initiates or accelerates a chemical reaction without itself being affected.
Term
Chemical Change
Definition
Changes that take place on the molecular level. A chemical change produces a new substance.
Term
Chemical Interactions
Definition
Caused when two or more chemicals, or the chemical and its container are incompatible.
Term
Compound, mixture
Definition
Separate elements that bond together to form compound mixture, they have a tendency to break down into their component parts, sometimes in an explosive manner.
Term
Concentration
Definition
When dealing with corrosives, the amount of acid or base is compared to the amount of water present.
Term
Critical Temperature
Definition
The minimum temperature at which a gas can be liquefied no matter how much pressure is applied. A gas cannot be liquefied above its critical temperature.
Term
Critical Pressure
Definition
The pressure that must be applied to bring a gas to its liquid state.
Term
Air Reactivity
Definition
Materials that can react or ignite if they are exposed to air.
Term
Corrosivity
Definition
A measure of a substance's tendency to deteriorate in the presence of another substance or in a particular environment.
Term
Dose
Definition
The concentration or amount of material to which the body is exposed over a specific time period.
Term
Half-life
Definition
Is the period of time it takes for a substance undergoing decay to decrease by half.
Term
Dose Response
Definition
The biological reaction caused by the does in the body. The degree of harm is directly related to the dose (time and amount)and its impact on bodily functions.
Term
Expansion Ratio
Definition
The amount of gas produced by a given volume of liquid at a given temperature.
Term
Flash Point
Definition
The minimum temperature at which a material gives off vapor in sufficient concentration to form an ignitable mixture with air and will not continue to burn.
Term
Fire Point
Definition
The temperature at which enough vapors are given off to support continuous burning.
Term
Flammable (Explosive) Range
Definition
The difference between the upper and lower limits.
Term
Organic
Definition
Pertaining to a class of chemical compounds that formerly comprised only those existing in or derived from plants or animals, but that now includes all other compounds of carbon.
Term
Lower Explosive Limit
Definition
The minimum concentration of vapor to air below which a flame will not propagate in the presence of an ignition source. Also known as "too lean to burn."
Term
Upper explosive limit (UEL)
Definition
Is the maximum vapor to air concentration above, which flame will not propagate. Also known as "too rich to burn"
Term
Halogenated Hydrocarbons
Definition
They are often more toxic than naturally occuring organic chemicals. They decompose into smaller, more harmful elements when exposed to high temperatures for long periods of time.
Term
Inhibitor
Definition
Added to products to control their chemical reaction with other products. If it is not added or escapes during an incident, the material will begin to polymerize, which creates a very dangerous situation.
Term
Ignition (Auto-ignition) Temperature
Definition
The temperature at which a material (solid, liquid, or gas) will self-ignite and sustain combustion in air without an external spark or flame.
Term
Instability
Definition
Materials that decompose spontaneously, polymerize, or otherwise self-react and generally considered unstable.
Term
Ionic and covalent compounds
Definition
Materials made through the sharing or transfer of electrons.
Term
Irritants (Riot Control Agents)
Definition
They cause respiratory distress and copious tearing that incapacitate a victim.
Term
Maximum Safe Storage Temperature (MSST)
Definition
The maximum temperature that an organic peroxide may be stored safely.
Term
Dissociation
Definition
The separation of a substance into two or more simpler substance, or of a molecule into atoms or ions, by the action of heat or a chemical process. Dissociation is usually reversible.
Term
Melting Point
Definition
The temperature at which a solid becomes a liquid allowing it to spread more readily.
Term
Freezing Point
Definition
The temperature at which a liquid converts to a solid.
Term
Miscibility
Definition
Refers to the tendency or ability of two or more liquids to form a uniform blend or to dissolve in eachother. A) Miscibility is complete solubility, B) Generally seen in liquids, C)Water and ethyl alcohol are miscible, oil and water are not.
Term
Nerve Agents
Definition
Substances that interfere with the central nervous system.
Term
Inorganic
Definition
Composed of matter that is not animal or vegetable; not having the organized structure of living things. Inorganic material lacks carbon chains.
Term
Oxidation Potential
Definition
The combining of anything with oxygen or the propensity to yield oxygen which will present a greater hazard.
Term
Persistence
Definition
Persistence refers to a chemical's ability to remain in the environment. The more persistent, the greater the propensity for it to remain harmful over a period of time.
Term
pH
Definition
The numerical measure of a solution's hydrogen ion concentration as related to acidity or alkalinity.
Term
Physical Change
Definition
The process when objects undergo a change that does not change their chemical properties.
Term
Physical State (solid, liquid, gas)
Definition
The characteristic form of a material at ambient temperature.
Term
Polymerization
Definition
Any process in which relatively small molecules, called monomers, combine chemically to produce a very large chain-like or network molecule, called a polymer.
Term
Radioactivity
Definition
Spontaneous emission of ionization radiation as a consequence of a nuclear reaction, or directly from the breakdown of an unstable nucleus.
Term
Alpha
Definition
Positively charged particle emitted by some radioactive materials and is not considered dangerous unless ingested.
Term
Beta
Definition
Can damage skin tissue, and they can damage internal organs if they enter the body. Full protective clothing, including positive pressure SCBA will protect against this type of RAD.
Term
Gamma
Definition
Causes skin burns and can severely injure internal organs; therefore, protective clothing is inadequate in preventing this RAD from harming the body.
Term
Water Reactivity
Definition
Describes the sensitivity of a material to water without the addition of heat or confinement.
Term
Riot Control Agents
Definition
Chemical compounds that temporarily make people unable to function by causing irritation to the eyes, mouth, throat, lungs, and skin.
Term
Saturated Hydrocarbons
Definition
Hydrocarbons that contain only single bonds. They are also called alkanes or paraffin hydrocarbons.
Term
Unsaturated Hyrdrocarbons
Definition
Materials that have at least one multiple bond between two carbon atoms somewhere in molecule, which causes them to be more hazardous. A) Those with at least one double bond are called alkenes and those with at least one triple bond are called alkynes.
Term
Aromatic Hydrocarbons
Definition
Materials that contain the benzene "ring" which is formed by six carbon atoms and contains double bonds. Its greatest hazard is toxicity.
Term
Self-accelerating decomposition temperature
Definition
When this temperature is reached by some portion of the mass of the organic peroxide, irreversible decomposition will begin A) this reaction can be violent, usually rupturing the vessel or container dispersing peroxide, liquid and gaseous decomposition products products considerable distance.
Term
Solubility
Definition
The ability of a substance to form a solution with water can be important when determining control methods. For example, gasoline is insoluble, while anhydrous ammonia is soluble.
Term
Solution
Definition
Mixture in which all of the ingredients are completely dissolved.
Term
Slurry
Definition
Pourable mixture of a solid and a liquid.
Term
Specific Gravity
Definition
The weight of a solid or liquid compared to an equal volume of water.
Term
Strength
Definition
The concentration of a solution. In corrosives, strength refers to the degree ionization of an acid or a base in water.
Term
Sublimation
Definition
The ability of a substance to change from the solid to the vapor phase without passing through a liquid phase.
Term
Temperature of a Product
Definition
Influences the hazards present and the measures taken to control an incident that involves that products.
Term
Toxic Products of Combustion
Definition
Byproducts of the comustion process that are harmful to humans. Some materials generate more highly toxic gases than others do; therefore, appropriate levels of protective clothing and equipment must be used to counter them.
Term
Vapor Density
Definition
Weight of a vapor compared to air.
Term
Vapor Pressure
Definition
The force exerted by the gas or vapor released by a liquid or solid substance in a closed container or space.
Term
Vesicants (Blister Agents)
Definition
These agents are extremely toxic, with the symptoms of exposure not appearing for minutes, hours, or days.
Term
Viscosity
Definition
Measure of the thickness of a liquid, determines how easily it flows.
Term
Volatility
Definition
Ease with which a liquid or solid can pass into the vapor state. This will affect the dispersment in air and expand the endangered area.
Term
Counts per Minute
Definition
Counts per minute and kilcounts perminute are measurements of RAD. It is the number of atoms in a given quantity of RAD material that are detected to have decayed in one minute.
Term
Immediately Dangerous to Life and Health (IDLH) Value
Definition
Maximum level to which a healthy worker can be exposed for 30 mins and escape without suffering irreversible health effects or impairment.
Term
Incubation Period
Definition
The latency between exposure to a pathogen and onset of symptoms.
Term
Infectious Dose
Definition
Amount of a pathogen necessary to manifest its pathogenicity.
Term
LC50
Definition
Amount of material in air that is expected to kill 50 percent of a group of test animals when administered in a specific time period.
Term
LD50
Definition
Causes death of 50 percent of a group of test animals exposed to it by any route other than inhalation.
Term
Parts Per Million
Definition
The ratio of the amount of one substance to the amount of another, expressed as a unit of solute dissolved in one million units of solution.
Term
Parts Per Billion
Definition
Number of units of one substance relative to one billion units of another.
Term
Permissible Exposure Limit (PEL)
Definition
Regulatory limits on the amount or concentration of a substance in the air. 95% of healthy adults will not suffer affects.
Term
Radiation Absorbed Dose (rad)
Definition
Equals the energy absorption of 100 ergs per gram of irradiated material. Largely obsolete due to centigray.
Term
Roentgen Equivalent Man (rem)
Definition
International unit of intensity of x-rays and gamma rays.
Term
Threshold limit value ceiling (TLV-C)
Definition
Max concentration to qhich a healthy adult can be exposed without risk of injury, and the exposure to higher concentrations should not occur.
Term
Threshold limit value short-term exposure limit (TLV-STEL)
Definition
Max average concentration, averaged over a 15-minute period, to which a healthy adult can be safely exposed for 15 mins four times a day.
Term
Threshold limit value time weighted average (TLV-TWA)
Definition
Max concentration averaged over 8 hours to which a healthy adult can be repeatedly exposed for 8 hours per day 80 hours a week.
Term
Reactivity
Definition
Substances propensity to release energy or undergo change, for example self reaction, polymerization or violent reaction.
Term
Three Types of Response Objectives
Definition
Offensive, Defensive, Nonintervention
Term
Response Objectives
Definition
Change applied stress, move stressor, move stressed system, shield stressed system
Term
Change Breach Size
Definition
Chill contents, limit stress levels, activate venting devices, mechanical repair
Term
Change Quantity Released
Definition
Change container position, minimize pressure differential, cap off breach, remove contents
Term
Change Size of Danger Zone
Definition
Barries, adsorbents, absorbents, diluents, reactants, overpack
Term
Change Exposures Contacted
Definition
Provide sheltering, begin evacuation, PPE
Term
Change Severity of Harm
Definition
Rinse off contamination, increase distance from source, provide shielding, provide prompt medical attention
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