Shared Flashcard Set

Details

Phosphorus sorption in soils
Phosphorus sorption in soils
25
Agriculture
Undergraduate 4
10/31/2016

Additional Agriculture Flashcards

 


 

Cards

Term
Plant roots absorb phosphorus from...
Definition
the soil solution
Term
In general, roots absorb phosphorus in the form of...
Definition
orthophosphate (PO43-)
Term
plants can also obtain certain forms of this phosphorous
Definition
organic
Term
Phosphorus moves to the root surface through...
Definition
diffusion
Term
this can reduce the movement of phosphorus from soil solution to roots
Definition
Compaction of soils under agriculture fields
Term
what Compaction of soils under agriculture fields can do to P in soil
Definition
reduce the movement of phosphorus from soil solution to roots
Term
what mycorrhizal fungi do for plants pertaining to P
Definition
the presence of mycorrhizal fungi, which develop a symbiotic relationship with plant roots and extend threadlike hyphae into the soil, can enhance the uptake of phosphorus, as well especially in acidic soils that are low in phosphorus
Term
P-sorption occurs when...
Definition
the orthophosphates, H2PO4- and HPO42-, bind tightly to soil particles
Term
Since phosphate is an anion, these particles will form strong bonds with phosphate.
Definition
particles that generate an anion exchange capacity
Term
some Particles with anion exchange capacity
Definition
-Aluminum and iron oxides
-Highly weathered kaolin clays (under acidic conditions)
-Amorphous materials.
Term
where particles with anion exchange capacity are commonly found
Definition
weathered soils
Term
why P-sorption can become a major issue to achieve high crop yields
Definition
because P-sorption results in a decrease of plant available phosphorus
Term
Factors that affect P-sorption
Definition
-soil mineral type
-amount of clay
-pH
-temperature
Term
how soil mineral type affects P-sorption
Definition
Mineralogy of the soil has a great effect on P-sorption
Term
the soils that tend to have the highest P-sorption and why
Definition
o Volcanic soils tend to have the greatest P-sorption of all soils since volcanic soils contain large amounts of amorphous material.
Term
why oxisols and ultisols have high P-adsorption capacities
Definition
because of large amounts of aluminum and iron oxides and highly weathered kaolin clays
Term
these soils have low P-sorption capacities
Definition
less weathered soils and organic soils
Term
how the amount of clay affects P-sorption and why
Definition
As the amount of clay increases in the soil, the P-sorption capacity increases as well. This is because clay particles have a tremendous amount of surface area for which phosphate sorption can take place.
Term
how pH affects P-sorption
Definition
At low pH, soils have greater amounts of aluminum in the soil solution, which forms very strong bonds with phosphate. In fact, a soil binds twice the amount of phosphorus under acidic conditions, and these bonds are five times stronger.
Term
how temperature affects P-sorption
Definition
Generally, P-sorption increases as temperature increases.
Term
Factors that decrease P-sorption
Definition
-Other anions, such as silicates, carbonates, sulfates, arsenate, and molybdate
-organic matter
-flooding
Term
how Other anions, such as silicates, carbonates, sulfates, arsenate, and molybdate affect P-sorption
Definition
They compete with phosphate for a position on the anion exchange site. As a result, these anions can cause the displacement, or desorption, of phosphate from the soil exchange site. Desorption causes phosphate availability in the soil solution to increase.
Term
how organic matter increases P availability
Definition
-First, organic matter forms complexes with organic phosphate which increases phosphate uptake by plants.
-Second, organic anions can also displace sorbed phosphate.
-Third, humus coats aluminum and iron oxides, which reduces P sorption.
-Finally, organic matter is also a source of phosphorus through mineralization reactions.
Term
how flooding affects P-sorption
Definition
• Flooding the soil reduces P-sorption by increasing the solubility of phosphates that are bound to aluminum and iron oxides and amorphous minerals.
Term
the 3 main mechanisms for phosphorus adsorption in soils
Definition
1: outer-sphere complexation
2: monodentate inner-sphere complexation
3: bidentate inner-sphere complexation
Supporting users have an ad free experience!