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According to published data (Richardson 2004), over thirty years ago, in the 1983 |
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the volumetric production of plastics surpassed metal and ceramic combined. and continues to surpass |
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in the year 2006, in the United States, the plastic industry was employed __ with an average income of___ |
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1.2 million persons with an average income of $37,000 per year. |
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Typical applications for Plastics industry include: |
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Aerospace Precision Engineering Automotive Engineering General Mechanical Engineering Design of Technical Equipment Construction Industry |
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Thermosets, thermoplastics |
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branch off of thermoplastics |
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Commodity Resins Engineering Resins |
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what makes cermaic materials |
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The mixture of metallic element light blue with five elements of carbon, nitrogen, oxygen, phosphorous and sulfurous. |
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what makes plastic materials |
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Plastic materials in today technology are the mixture of mostly six elements, hydrogen, carbon, nitrogen, oxygen, fluorine, & silicon |
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Depending on the goal, the added materials (additive) can be an additive added as a |
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Modifier Processing Aid Reinforcements Filler Others |
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are stabilizers that slowdown or stop oxidation of polymer. |
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Definition
are additives that helps prevent breakdown by ozone gas in the atmosphere |
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Solar radiation of polymers may results in |
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crazing, chalking, color changes, or loss of physical and chemical, electrical, or mechanical properties. |
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The additive added to a polymer specifically to enhance a mechanical properties |
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Definition
Coupling agents Curing agents Flame retardants Foaming/ Blowing agents Impact modifiers |
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Plasticizers Heat stabilizers Lubricants Ant blocking Solvents |
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Long fibers Short fibers Others |
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Particulate reinforcement |
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Glass base particulate Ceramic base particulate Others |
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Fibrous reinforcement Flack reinforcement Particulate reinforcement |
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are an additive added to a plastics primarily to increase the bulk and reduce the cost. |
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Thermosetting hence are the plastics witch undergo the heat softening once. Upon polymerization, they retain their form permanently. |
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divisions of thermosetting |
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Thermosets, and elastomer |
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Over ___ percentage of the current plastics are carbon based plastics |
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Definition
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Term
he five most common type of thermosetting matrix are: |
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T Polyester, Phenolics, Epoxy, Polyimide, and Bismaleimide |
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Disadvantages of polyurethane |
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Definition
Poor thermal capability 2. Toxic (isocyanates are used) 3. Poor weatherability 4. Subject to attack by solvents |
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Disadvantages of Phenolics |
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Definition
1. Need fillers for moldings 2. Poor resistance to bases and oxidizers 3. Volatiles released during cure (a condensation polymer) 4. Dark color (due to oxidation discoloration) |
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1. Comparatively low cost 2. Suitable for use at temperatures to 400°F (205°C) 3. Excellent solvent resistance 4. Rigid 5. Good compressive strength 6. High resistively to abrasions 7. Self-extinguishing 8. Very good electrical characteristics |
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A thermosetting resins made by reacting pyromellitic diahydride with aromatic diamines. This polymer is characterized by rings of four carbon atoms tightly bounded together. |
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Disadvantage of Polyimides |
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Definition
Difficult to process Expansive Limited Structural usage Limited electrical usage |
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Disadvantages of Urea-Formaldehyde |
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Definition
1. Must be filled for successful molding 2. Long-term oxidation resistance is poor 3. Attacked by strong acids and bases 4. Uncured, partially polymerized plastics and foams degas |
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Advantages of Urea-Formaldehyde |
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Definition
1. Good hardness and scratch resistance 2. Comparatively low cost 3. Wide color range 4. Self-extinguishing 5. Good solvent resistance |
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Disadvantages of Melamine-Formaldehyde |
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Definition
1. Must be filled for successful molding 2. Poor long-term oxidation resistance 3. Subject to attack by strong acids and bases |
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Advantages of Melamine-Formaldehyde |
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Definition
1. Good hardness & scratch resistance 2. Comparatively low cost 3. Wide color range 4. Self-extinguishing 5. Good solvent resistance |
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Two Broad Categories of epoxy |
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Definition
250 oF curing temperature with 175 oF Service Temperature 350 oF curing temperature with 275 oF Service temperature. |
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Definition
1. Wide range of cure conditions, from room temperature to 350°F (178°C) 2. No volatiles formed during cure 3. Excellent adhesion 4. Can be cross-linked with other materials 5. Suitable for all thermosetting processing methods |
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1. Poor oxidative stability; some moisture sensitivity 2. Thermal stability limited to 350-450°F(178-232°C) 3. Many grades are expensive |
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are defined as solid materials of any of a large and varied group of substances consisting wholly or in part of combination of carbon/silicon with oxygen, nitrogen, hydrogen and other organic or inorganic elements. |
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are defined as materials of any of a large and varied group of substances consisting wholly or in part of combination of carbon/silicon with oxygen, nitrogen, hydrogen and other organic or inorganic elements |
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Polymeric (plastic) materials |
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Definition
Any of various natural or synthetic materials chemically created from organic substances, which are not conductive of: Heat and electricity |
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Definition
Polyethylene Polypropylene Polystyrene Polycarbonate Nylon |
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Behavior of Polymeric Material |
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Definition
Do not conduct heat Do not conduct Electricity Have a light weight Burn or degrade up on heating |
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Polyethylene, a typical of polymer is the result of the attachment of a ethylene vinyl, a monomer to produce a polymer known as polyethylene. |
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Nylon a well known plastic was discovered by the Du-Pont lab in New York and London at the same time. |
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Thermoplastics is the mixture of a primary and secondary bonds. |
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Definition
The polymerization of thermoplastics involve with three steps: Initiation, Start Propagation, Growth Termination, stop |
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Definition
Stereoisomerism is refers to the arrangement of radicals within a given molecule |
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Definition
Atactic arrangement is the random arrangement of monomer within the structure of a polymer |
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Definition
Syndiotactic arrangement is a regular Alternation of the radical within a molecular structure |
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Definition
Isotactic is the placement of the monomer with in the structure of polymer is the same arrangement. |
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