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SFPN Lab 7
SFPN Lab 7
22
Agriculture
Undergraduate 4
10/16/2016

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Term
ammonia volatilization
Definition
The process of ammonia diffusion from the soil surface to the atmosphere
Term
ammonia volatilization is a complex process often associated with...
Definition
surface-applied animal manures and N fertilizers
Term
ammoniacal N
Definition
NH4+ and NH3
Term
For ammonia volatilization to occur, ammoniacal N (NH4+ and NH3) must be...
Definition
either initially present in the applied material, or generated during manure or fertilizer transformations
Term
when animal manures can release additional ammoniacal N
Definition
during organic N decomposition (N mineralization or ammonification)
Term
a fertilizer that contains ammoniacal N
Definition
some such as ammonium nitrate
Term
a fertilizer that can release ammoniacal N after application to soil
Definition
urea
Term
some environmental factors that generally enhance the conversion of organic N from fertilizers or manures to NH4+
Definition
higher temperature and soil water content
Term
what higher temperature and soil water content does for the conversion of organic N from fertilizers or manures to NH4+
Definition
generally enhances the conversion of organic N from fertilizers or manures to NH4+
Term
The ammoniacal N from animal manures or fertilizers is initially released into ______, where it is partitioned into ______
Definition

the soil solution

NH4+ and NH3

Term
The ammoniacal N from animal manures or fertilizers is initially released into the soil solution, where it is partitioned into NH4+ and NH3 depending on...
Definition
pH and temperature
Term
pH and temperature vs. amount of NH3
Definition
As pH and temperature increase, the proportion found as NH3 increases
Term
effect of rain, irrigation, or tillage on ammoniacal N
Definition
any rain, irrigation, or tillage that moves the ammoniacal N into the soil usually enhances adsorption of NH4+ and eliminates or reduces NH3 losses
Term
what has to happen for NH3 to be lost as gas
Definition
some of the NH3 dissolved in the soil solution has to be converted to gaseous NH3, a process that is controlled by Henry’s Law constant
Term
Henry's constant
Definition
describes the proportion of NH3 that is in the soil air compared to the adjacent soil solution
Term
some reasons NH3 volatilization increases when soil temperature rises
Definition

1) the conversion of organic N to NH4+ increases

2) the proportion of total ammoniacal N as NH3 increases

3) the proportion of NH3 in the soil air increases.

Term
the effect of the decomposition of animal manures and the hydrolysis of urea fertilizers
Definition
consume H+ ions from the soil, which in turn can lead to a pH increase
Term
hydrogen buffering capacity (HBC) vs. NH3 loss
Definition
soils with a large HBC commonly show smaller NH3 losses than soils with a small HBC
Term
some reasons losses of NH3 are increased in wetter areas
Definition

1) release of NH4+ from organic sources such as urea is enhanced under wetter conditions

2) a greater proportion of the NH4+ is not adsorbed by the soil exchange sites and remains in the soil solution at higher soil water contents.

Term
why some plant damage may occur if urea is banded with the seed
Definition
because of ammonium toxicicity
Term
why the rate of urea hydrolysis matters
Definition
because a fast rate reduces the time available for urea and ammoniacal N to diffuse deeper into the soil when surface-applied
Term
objective of this lab number 7
Definition
to evaluate the effect of soil water content and temperature on ammonia volatilization from surface-applied urea.
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