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Wine Fining and Additives
Wine Fining Treatments and their effects, FST 467
17
Agriculture
Undergraduate 4
06/08/2010

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Term
Why do we fine?
Definition
Accelerate precipitation of suspended particles

stabilize wines against haze formation (protein haze)

eliminate off odors (sulfides, oxidized aromas)

remove astringent phenolics, remove oxidized compounds
Term
Considerations of Fining
Definition
It is an aid and should only be used if necessary

fining agents are not highly specific

vineyard and winemaking "adjustments" can minimize need for fining operations (must nutrient, oxidation prevention, extraction during ferment)
Term
General Principals behind fining
Definition
based on electrostatic or hydrophobic interactions (rarely covalent)
Term
Tannin-Protein Interactions
Definition
hydrogen bonds and hydrophobic interactions

hydrogen bonds between phenolic hydroxyl group and peptide bonds of proteins

reversible

dependent on tannin size, structure and charge

pH influenced (higher pH more charged Flavanol)
Term
Categories of Fining Agents
Definition
Protein: gelatin, isinglass, casein, albumen

Carbons: Activated carbon

Synthetic: PVPP

Earths: Bentonite
Term
Protein fining agents
Definition
amino acid composition, structure, size and charge play a role,

high proline content has an affinity for tannins

proteins usually have a + charge at 3.5pH

low temperatures favor precipitation

in general more protein=less tannins, but not linear
Term
Protein Effect on Phenolics
Definition
-minimal decrease in color
-mainly effects larger tannins such as condensed tannins due to larger charge density
-minimal removal of smaller MW phenolics
Term
Gelatin
Definition
produced from pig skins and animal bones

high proline content

positively charged

preferentially binds to larger molecules-
good to remove astringency

may be too agressive and make thin, bitter, hard wine
Term
Casein
Definition
absorbs negativley charged particles as it settles

removes oxidized color and aroma, removed bittering compounds
Term
Isinglass
Definition
sturgeon bladder, collagen based

removes tannin, phenols, color and yeast as well as general clarification of white wines

sometimes used to aid riddling

gentle fining, less tannins removed
Term
Egg White/ Albumen
Definition
gentle, polishing fining agent for reds,

3-8 whites per barrel
Term
Blood
Definition
ox blood, used to reduce tannins,

no longer common
Term
Activated Carbon
Definition
works by physical absorbtion

steam activated can remove off odors like H2S and ethyl acetate

can be too powerful

acid activated can decolorize wine

-dirty, hard to handle and nonselective
Term
PVPP
Definition
binds specifically with low MW polyphenols

insoluble- polyphenols absorb onto surface and precipitate

minimizes aroma stripping

used for removal of color, bitterness and some oxidized flavors

can be used to teat botrytis infected grapes with bentonite
Term
PVPP
Definition
binds specifically with low MW polyphenols

insoluble- polyphenols absorb onto surface and precipitate

minimizes aroma stripping

used for removal of color, bitterness and some oxidized flavors

can be used to teat botrytis infected grapes with bentonite
Term
Bentonite
Definition
Claylike material, hydrated Aluminum Silicate

works by electrostatic interactions

large surface area for - charge

must be hydrated

protein stability, clarification, removal of oxidized color and aroma (due to rot)
Term
Copper Sulfate
Definition
combines with H2S and mercaptans and drops out of solution

(does NOT get disulfides)

may remove desired thiols

legal limit, .5mg/L copper ion
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