Term
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Definition
Alkyl Halides- Hydrohalogenation
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Term
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Definition
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Term
alkene --Br2/CH2Cl2 or CCl4
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Definition
Halogenation trans- 1,2 dibromides
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Term
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Definition
Bromohydrin Formation- Trans 1,2-bromohydrins |
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Term
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Definition
Catalytic Hydrogenation Alkanes |
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Term
alkene -- KMnO4, NaOH, or OsO4 |
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Definition
Cis Hydroxylation cis 1,2 diols |
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Term
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Definition
Oxidative Cleavage ketones or acids |
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Term
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Definition
epoxide formation epoxides |
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Term
alkyne-- H2 & lindlar catalyst |
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Definition
catalytic hydrogenation cis alkenes |
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Term
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Definition
catalytic hydrogenation alkanes |
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Term
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Definition
deprotenation of terminal alkyne acetylide anion |
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Term
aromatics-- X2, FeX3, or AlX3 |
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Definition
Halogenation halogenated aromatic |
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Term
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Definition
Nitration Nitrated Aromatic |
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Term
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Definition
Sulfonation sulfonated aromatic |
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Term
aromatics-- tertiary alkyl halide, FeX3 |
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Definition
Alkylation alkylated aromatic |
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Term
aromatics-- R-CO-CL, FeCl3, or AlCl3 |
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Definition
Acylation acylated aromatic |
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Term
Aromatic w/one benzylic hydrogen --KMnO4 |
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Definition
Side chain oxidation Benzoic Acid |
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Term
Nitroaromatics-- H2 & Pd/C or iron and tin reagents |
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Definition
reduction of Nitroaromatics Anilines |
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Term
2nd or 3rd alkyl halide -- weak Nu (solvent) |
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Definition
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Term
methyl, primary or secondary alkyl halide-- good Nu |
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Definition
SN2 inversion of configuaration |
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Term
secondary or tertiary alcohol-- weak base |
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Definition
E1 alkene at most substituted carbon |
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Term
alkyl halide- strong/bulky base |
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Definition
E2 alkene/alkyne at most substituted carbon |
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Term
aldehyde -- NaBH4/MeOH or LAH/H30+ |
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Definition
Reduction of Aldehydes primary alcohol |
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Term
ketone -- NaBH4/MeOH or LAH/H30+ |
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Definition
Reduction of Ketones secondary alcohol |
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Term
Carboxylic acids/derivatives-- LAH H3O+ |
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Definition
Reduction of Carboxylic acids/derivatives primary alcohol |
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Term
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Definition
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Term
secondary alcohol -- PCC or CrO3 |
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Definition
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Term
primary alcohol-- KMnO4 or CrO3 |
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Definition
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Term
2nd-3rd alkyl halide or alcohol -- H2SO4 or H3PO4 |
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Definition
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Term
primary or 2nd alcohol -- isobutylene gas&acid catalyst |
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Definition
t-butyl ether synthesis t-butyl ether |
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Term
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Definition
ether cleavage alkyl bromide or iodide/alcohol |
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Term
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Definition
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Term
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Definition
Synthesis of Alkyl Bromides Alkyl bromides |
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Term
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Definition
Synthesis of Alkyl Alkyl Chlorides |
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Term
alcohols-- tosyl chloride |
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Definition
synthesis of tosylates tosylates |
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Term
Aldehyde or Ketone-- Alcohol, H+ |
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Definition
Hemiacetal/Acetal Formation Hemiacetal/Acetal |
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Term
Aldehyde or Ketone-- primary amine, H+ |
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Definition
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Term
Imines-- H2 and Pd/C or NaBH4 |
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Definition
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Term
Ethylene Oxide-- a.)RMgBr/ether b.) H3O+ |
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Definition
Alcohol Synthesis- Grignard primary alcohol w/2C's |
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Term
Aldehydes-- a.)RMgBr/ether b.) H3O+ |
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Definition
Alcohol Synthesis- Grignard Secondary alcohol |
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Term
Formaldehyde-- a.)RMgBr/ether b.) H3O+ |
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Definition
Alcohol Synthesis- Grignard primary alcohol w/1C's |
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Term
Ketones-- a.)RMgBr/ether b.) H3O+ |
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Definition
Alcohol Synthesis- Grignard tertiary alcohol |
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Term
CO2-- a.)RMgBr/ether b.) H3O+ |
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Definition
Alcohol Synthesis- Grignard Carboxylic acid |
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Term
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Definition
Formation of Acid Chloride |
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Term
Acid Chloride-- Carboxylate anion |
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Definition
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Term
Carboxylic acid and alcohol -- acid catalyst |
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Definition
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Term
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Definition
Hydrolysis Carboxylic Avid/Amine |
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Term
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Definition
Hydrolysis carboxylic acid and alcohol |
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Term
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Definition
syn. of alcohols primary alcohol |
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Term
ester-- RMGBr/ether and H3O+ |
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Definition
syn. of alcohols tertiary alcohol |
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Term
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Definition
hydrolysis of acid chloride |
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Term
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Definition
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Term
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Definition
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Term
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Definition
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Term
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Definition
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Term
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Definition
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Term
methyl, primary or secondary alkyl halide-- NaCN |
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Definition
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Term
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Definition
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Term
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Definition
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Term
Ketone or Aldehyde-- X2/HX |
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Definition
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Term
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Definition
syn. of carboxylic acids, Haloform |
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Term
aldehdes or ketones--NaOH & EtOH H3O+ |
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Definition
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Term
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Definition
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Term
B-Keto ester -- a.) NaOEt, EtOH; b.) R-X H3O+ &heat |
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Definition
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Term
Beta-di ester-- a.) NaOEt, EtOH; b.) R-X H3O+ &heat |
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Definition
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Term
a,b-unsaturated compound and nucleophile |
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Definition
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Term
carbonyl compound with a-hyrdogen--base |
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Definition
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Term
carbonyl compound with a-hyrdogen-- acid |
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Definition
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Term
alkene-- a.) mcpba b.) acid or base (aq) |
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Definition
formation of trans diols (epoxide ring opening) |
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