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Chapter 19-21
Reagents
19
Organic Chemistry
Undergraduate 2
03/30/2011

Additional Organic Chemistry Flashcards

 


 

Cards

Term
Gringard Reagents 
Definition

1)Mg

2)CO2

3)H2O

Term

Reduction of Aldehydes and Ketones to Alcohols Reagents? Reduce All?

 

Definition

1)LiAlH4, Et2O

2)H2O

 

NaBH4

MeOH

Term

Reagents of the reduction of Amides?

 

Definition

1) LiAlH3, Et2O

2) H2O

Term

Reagents to reduce Esters to Aldehydes?

 

Definition

1)DIBAL-H, CH2Cl2 -78C

2) H2O

Term

Reagents that Oxidize ketones to esters?

 

Definition
RCO3H, H2SO4
Term

Reagents of the reaction of gringard and organolithium with ketones and aldehydes?

 

Definition

1) R-M

2)H3O+

 

(M=MgBr)

Term

Reagents of silyl ether protective groups?

 

Definition

R3SiCl

pyr

Term

Reagents to deprotection?

 

Definition

Bu4NF

THF

Term

Reagents to the reation of acid chloride with gilman?

 

Definition

R2CuLi

the H3O+

Term

Reagents to organometallies with carboxylic acid derivatives?

 

Definition

R-M (2eq)

Then NH4Cl

 

(M=MgBr)

Term

Reagents of organometallics with alpha and beta-unsaturated carbonyls?

1-2?

3-4?

 

Definition

R-MgBr

then H3O+

 

R2CuLi

the H3O+

Term
mCPBA
Definition
Double bond to epoxide
Term
HCl
Definition
Opens up double bond and adds Cl
Term
O3
Definition
Breaks double bonds and forms ketone
Term
PBr3
Definition
Alcohol to Br
Term

Br2

FeBr3

Definition
Adds Br to benzene
Term

PCC

CH2Cl2

Definition
Alcohol to aldehyde
Term
Jones
Definition
Alcohol to ketone
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