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Chapter 7
Wade, 8th Ed. FC
14
Organic Chemistry
Undergraduate 2
10/28/2012

Additional Organic Chemistry Flashcards

 


 

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Term
Alkene
Definition
A hydrocarbon with one or more carbon-carbon double bonds
Term
Allyl Group
Definition
A vinyl group plus a methylene group: CH2=CH-CH2-
Term
Bredt's Rule
Definition
A stable bridged bicyclic compound cannot have a double bond at a bridgehead position unless one of the rings contains at least eight carbon atoms
Term
Catalytic Cracking
Definition
The heating of petroleum products in the presence of a catalyst (usually an aluminosilicate mineral), causing bond cleavage to form alkenes and alkanes of lower molecular weight
Term
dehalogenation
Definition
The elimination of a halogen (X2) from a compound. Dehalogenation is formally a reduction.
Term
Dehydration
Definition
the elimination of water from a compound; usually acid-catalyzed
Term
Dehydrogenation
Definition
The elimination of hydrogen from a compound; usually done in the presence of a catalyst
Term
Dehydrohalogenation
Definition
The elimination of a hydrogen halide (HX) from a compound; usually base-promoted
Term
Double-bond Isomers
Definition
Constitutional isomers that differ only in the position of a double bond. Double-bond isomers hydrogenate to give the same alkane
Term
Element of Unsaturation
Definition
A structural feature that results in two fever hydrogen atoms in the molecular formula. A double bond or a ring is one element of unsaturation; a triple bond is two elements of unsaturation
Term
Geminal Dihalide
Definition
A compound with two halogen atoms on the same carbon atom
Term
Heteroatom
Definition
Any atom other than carbon or hydrogen
Term
Hofmann Product
Definition
The least highly substituted alkene product
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