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Families of Carbon Compounds
This set of flashcards is designed to help students study terms and structures related to families of organic comounds.
59
Organic Chemistry
Undergraduate 2
01/15/2013

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Term
Alkanes
Definition
Hydrocarbons having only single bonds between carbon atoms. Saturated. Acyclic examples have the general molecular formula CnH2n+2
Term
Alkenes
Definition
Hydrocarbons having at least one double bond between carbon atoms. Unsaturated. Acyclic examples with one double bond have the general molecular formula CnH2n
Term
Alkyl Group
Definition
The designation given to a fragment of a molecule hypothetically derived from an alkane by removing a hydrogen atom. Names end in -yl. Often designated generically in a molecule with the letter R.
Term
Alkynes
Definition
Hydrocarbons having at least one triple bond between carbon atoms. Unsaturated. Acyclic examples with one triple bond have the general molecular formula CnH2n-2.
Term
Aromatic Compounds
Definition
A cyclic compound containing delocalized electrons within the ring. Often derived from benzene.
Term
Carbonyl Group
Definition
A functional group consisting of a carbon atom double bonded to an oxygen atom.
Term
Delocalized Electrons
Definition
Electrons that are dispersed through a molecule or part of a molecule and not fixed in place. Stabilize a compound.
Term
Dipole
Definition
The characteristic of a polar molecule where one end or side is somewhat positive and another is somewhat negative.
Term
Dipole Moment
Definition
A physical property associated with a polar molecule that describes the extent of polarity of the compound. Can be calculated by multiplying the charge (e) in electrostatic units by the distance (d) that separates them (m = e x d)
Term
dipole-dipole forces
Definition
An interaction between molecules having permanent dipoles. Otherwise stated as an interaction between polar molecules.
Term
Dispersion forces
Definition
Weak forces that attract between nonpolar molecules and small parts of the same molecule.
Term
Functional Group
Definition
The particular group of atoms in a molecule that primarily determines how the molecule reacts.
Term
Haloalkane
Definition
aka Alkyl Halide. A molecule where one hydrogen bonded to an sp3 hybridized carbon atom has been replaced by a halogen. Classified by the carbon bonded to the halogen as primary, secondary, or tertiary.
Term
Heteroatom
Definition
Atoms such as oxygen, nitrogen, sulfur, and that halogens that form bonds to carbon and have unshared pairs of electrons.
Term
Hydrocarbons
Definition
A molecule containing only hydrogen and carbon atoms.
Term
Hydrogen Bond
Definition
A strong dipole-dipole interaction that occurs between a hydrogen bonded to a small electronegative atom (O, N, F) and the nonbonding electron pairs on other such electronegative atoms. Look for O-H, N-H, or H-F bonds in a molecule.
Term
Hydrophilic Group
Definition
A polar group that seeks an aqueous environment.
Term
Hydrophobic Group
Definition
A nonpolar group that avoids an aqueous surrounding and seeks a nonpolar environment. Also referred to as lipophilic group.
Term
Intermolecular Forces
Definition
Also known as van de Waals Forces. Forces that act between molecules because of permanent or temporary electron distributions. Can be attractive or repulsive.
Term
Ion-dipole Forces
Definition
The interaction of an ion with a permanent dipole.
Term
Kekulé Structure
Definition
A structure in which lines are used to represent bonds. Benzene is often represented this way using a hexagon of carbon atoms with alternating double and single bonds around the ring and one hydrogen attached to each carbon atom.
Term
Methylene Group
Definition
The -CH2- group.
Term
Nonpolar Covalent Bond
Definition
A covalent bond where the electrons are equally shared between the atoms of the bond. Usually found between nonmetals with similar or the same electronegativities.
Term
Polar Covalent Bond
Definition
A covalent bond where the electrons are NOT equally shared because of differing electronegativities between the bonded atoms.
Term
Polar Molecule
Definition
A molecule with a dipole moment.
Term
Primary Carbon
Definition
A carbon that has only one other carbon atom bonded to it.
Term
Saturated Compounds
Definition
A compound that contains the maximum number of hydrogen atoms per carbon in the molecule. Does not contain any multiple bonds.
Term
Secondary Carbon
Definition
A carbon that has two other carbon atoms bonded to it.
Term
Tertiary Carbon
Definition
A carbon that has three other carbon atoms bonded to it.
Term
Unsaturated Compounds
Definition
A carbon atom that does not contain the maximum number of hydrogens per carbon atom. Contains multiple bonds.
Term
R
Definition
A symbol used to designate an alkyl group. Often used to symbolize any organic group.
Term
Benzene
Definition
The prototypical aromatic compound having the molecular forula C6H6.
Term
Quaternary Carbon
Definition
A carbon that has four other carbon atoms bonded to it.
Term
Ketone
Definition
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Term
Aldehyde
Definition
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Term
Carboxylic Acid
Definition
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Term
Ester
Definition
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Term
Amide
Definition
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Term
Benzyl Group
Definition
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Term
Butyl Group
Definition
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Term
Ether
Definition
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Term
Ethyl Group
Definition
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Term
Isobutyl Group
Definition
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Term
Isopropyl Group
Definition
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Term
Methyl Group
Definition
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Term
Nitrile
Definition
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Term
Phenyl Group
Definition
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Term
Primary Alcohol
Definition
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Term
Primary Alkyl Halide
Definition
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Term
Primary Amine
Definition
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Term
Propyl Group
Definition
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Term
sec-butyl group
Definition
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Term
Secondary Alcohol
Definition
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Term
Secondary Alkyl Halide
Definition
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Term
Secondary Amine
Definition
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Term
tert-butyl group
Definition
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Term
Tertiary Alcohol
Definition
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Term
Tertiary Alkyl Halide
Definition
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Term
Tertiary Amine
Definition
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