Term
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Definition
Def: adds H and X across DB
Reagents: H and Halogen
Regio: Markovnikov
Stereo: Chirality center |
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Term
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Definition
Def:addition of water over double bond
Reagents:H3O+
Regio: Markovnikov
Stereo: Chirality |
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Term
| Oxymercuration-Demurcuration |
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Definition
Def: Adds water over double bond when rearrangement is possible
Reagents: Hg(Oac)2
Regio: Markovnikov
Stereo: ? |
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Term
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Definition
Def: Places OH at less substituted.
Reagents: BH3
Regio: Anti Markovnikov
Stereo: Syn addition |
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Term
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Definition
Def:Adds H2 across double bond when metal
Reagents: H2 and metal cat (or wilkinsons)
Regio: irrelevent
Stereo: Syn addition, notice chirality |
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Term
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Definition
Def: Addition of Br2 or Cl2 across alkene
Reagents: Br2 or Cl2
Regio: irrelevant
Stereo: Anti Addition |
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Term
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Definition
Def: Adds Br or Cl and OH across double bond
Reagents: Br2 or Cl2 WITH H2O
Regio: Markovnikov
Stereo:Anti addition |
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Term
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Definition
Def: OH and OH across double bond
Reagents:epoxide, MCPBA/H3O+
Regio: irrelevent
Stereo: Anti |
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Term
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Definition
Def: OH groups across double bond
Reagents: Na2SO3/H20 or NAHSO3/H20
Regio: irrelevent
Stereo:syn |
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Term
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Definition
Def: Breaks a double bond and adds O
Reagents: O3/(DMS or ZNH2O)
Regio:irrelevent
Stereo:irrelevent |
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