Term
|
Definition
-Adds X to most subbed
-Adds H to least subbed
-Haloalkane |
|
|
Term
|
Definition
-Adds OH to most subbed
-Adds H to least subbed
-Alkanol |
|
|
Term
|
Definition
-Adds trans X's to each double bond carbon
-Dihaloalkane |
|
|
Term
|
Definition
-Trans addition
-X to least subbed
-OH to most subbed
-haloalkanol |
|
|
Term
| Alkene ---1. Hg(OAc)2, H2O 2. NaBH4--> |
|
Definition
-OH added to most subbed
-H added to least subbed
-alkanol
|
|
|
Term
| Alkene ---1. BH3 2. H2O2, NaOH---> |
|
Definition
-OH added to least subbed
-H added to most subbed
-alkanol |
|
|
Term
| Alkene ----1. OsO4 2. NaHSO3, H2O---> |
|
Definition
-Cis OH's added to double bond carbons
-alkandiol |
|
|
Term
| Alkene ---1.O3 2. (Ch3)2S---> |
|
Definition
-Cleaves double bond
-adds =O where dbl bond was
-Keto/enol tautomers
-ethers and aldehydes |
|
|
Term
| alkene ------H2, Pt------> |
|
Definition
-double bond reduced and H's added
-alkane |
|
|
Term
| Terminal alkyne -----NaNH2-----> |
|
Definition
-Removes terminal H and creates anion
-can add to chain length with haloalkane
-akyne anion |
|
|
Term
| Alkene --X2--> ----NaNH2 in NH3(l)---> |
|
Definition
-rxn 1 yields dihaloalkane
-rxn 2 yields alkyne
-alkyne |
|
|
Term
| Alkyne ---X2--> ---X2------> |
|
Definition
-Rxn 1 yields trans dihaloalkene
-Rxn 2 yields tetrahaloalkane
-tetrahaloalkane |
|
|
Term
| Alkyne ----HX----> ------HX-----> |
|
Definition
-Rxn 1 yields haloalkene on most subbed
-H added to least subbed
-Rxn 2 yields dihaloalkane on the most subbed
-H added to least subbed
-dihaloalkane |
|
|
Term
| Internal alkyne -----1.BH3 2.H2O2, NaOH---> |
|
Definition
-OH added to either carbon
-Keto/enol tautomerization
-ketone |
|
|
Term
| Terminal alkyne ----1.(sia)2BH 2.H2O2, NaOH---> |
|
Definition
-OH added to least subbed
-Keto/enol tautomerization
-aldehyde |
|
|
Term
| Alkyne ----H2SO4, HgSO4, H2O-----> |
|
Definition
-OH added to most subbed
-H to least subbed
-Keto/enol tautomerization
-ketone or aldehyde |
|
|
Term
| Alkyne ----H2, Pt-------> |
|
Definition
-H's added to all bonds
-reduced all the way
-alkane |
|
|
Term
| Alkyne -----H2, Lindlar------> |
|
Definition
-Syn H's added
-Only one reduction step
-cis alkene |
|
|
Term
| Alkyne -----1.BH3 2.CH3COOH-----> |
|
Definition
-syn H's added to triple bond
-cis alkene |
|
|
Term
| Alkyne ------Na in NH3(l)------> |
|
Definition
-Anti H's added to triple bond
-only 1 reduction step
-trans alkene |
|
|
Term
| Alkane -------X2, hv------> |
|
Definition
-X replaces most subbed C's H
-haloalkane |
|
|
Term
| Alkyne ----NBS, CH2Cl2, hv----> |
|
Definition
| -Br replaces H on allylic C |
|
|
Term
| Alkene -----O2, R•-------> |
|
Definition
| -OOH replaces H on allylic Carbon |
|
|
Term
| Alkene -----HBr, Peroxides-----> |
|
Definition
-double bond breaks
-H added to most subbed
-Br added to least subbed
-haloalkane |
|
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