Term
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Definition
-H and -OH are removed from adjacent carbon atoms of the same alcohol to produce an alkene and H2O
H+ catalyst
H OH.
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-C-C-
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Becomes
C=C + H2O |
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Term
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Definition
The major product is the one that forms by removing the hydrogen from the carbon atom that has the smaller number of hydrogen atoms.
2-butanol 90% becomes 2-Butene, 10% 1-Butene
CH3-CH-CH-CH3
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H OH
CH3-CH=CH-CH3 + H2O (90%) |
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Term
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Definition
Ethers form when the dehydration of alcohols occur at a low temp in the presence of an acid catalyst. 130C. An H is removed from one side, -OH removed from the other. The 2 molecules are then bound to the remaining O. |
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Term
Formula for the formation of an ether |
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Definition
Dehydration of 2 alcohols. Ether remains and H2O
CH3-OH + CH3-OH -> CH3-O-CH3 + H2O
Methanol Methanol Dimethyl Ether
One H is removed, on -OH is removed forming H2O. The 2 alcohols are bound to the remaining ether. |
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Term
Product of Oxidation of a primary alcohol |
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Definition
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Term
Oxidation of a primary alcohol process |
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Definition
Remove 2 hydrogen atoms, one from -OH and one from the carbon bonded to the -OH. The oxygen that makes the H2O is taken from the Oxidizing agent.
Methanol Methanal
CH3-OH [O] -> H-C-H + H2O
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O |
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Term
Secondary Alcohol oxidation product? |
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Definition
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Term
Secondary alcohol oxidation process |
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Definition
One hydrogen removed from the -OH and one from the cabon bonded to the -OH group. Ketone with a carbon-oxygen double bond attached to the alkyl groups on both sides. Water is formed from the 2 -H removed and an O from the oxidizing agent.
CH3-CH-CH3 [O] -> CH3-C-CH3 + H2O
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O O |
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Term
Aldehydes to Carboxylic Acid |
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Definition
An additional O adds to the aldehyde attached to the hydrogen remaining. The O is taken from the oxidizing agent.
Acetaldehyde Ecetic Acid
CH3-C-H [O] -> CH3-C-OH
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O O |
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Term
Oxidation of Thiols product |
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Definition
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Term
Oxidation of Thiols reaction |
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Definition
2 thiols [O] combine to create a disulfide + water
Oxidation through loss of Hydrogen atoms
CH3-S-H + CH3-S-H [O] -> CH3-S-S-CH3 + H2O
Methanethiol x2 Dimethyl disulfide |
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Term
Primary Alcohol second oxidation product after aldehyde? |
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Definition
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